
#(C) 2025 by FIZ Karlsruhe - Leibniz Institute for Information Infrastructure.  All rights reserved.
data_423127-ICSD
_database_code_ICSD 423127
_audit_creation_date 2012-02-01
_chemical_name_common 'Lithium indium ditungstate'
_chemical_formula_structural 'Li In W2 O8'
_chemical_formula_sum 'In1 Li1 O8 W2'
_chemical_name_structure_type LiFe(WO4)2
_exptl_crystal_density_diffrn 7.45
_citation_title

;
Host-sensitized emission of Li In W2 O8 wolframites : From red-Eu(3+) to white
Dy(3+) phosphors
;
loop_
_citation_id
_citation_journal_full
_citation_year
_citation_journal_volume
_citation_page_first
_citation_page_last
_citation_journal_id_ASTM
primary 'Journal of Solid State Chemistry' 2011 184 2566 2570 JSSCBI
loop_
_citation_author_citation_id
_citation_author_name
primary 'Naidu, S.A.'
primary 'Boudin, S.'
primary 'Varadaraju, U.V.'
primary 'Raveau, B.'
_cell_length_a 9.58096(2)
_cell_length_b 11.59048(2)
_cell_length_c 4.95690(1)
_cell_angle_alpha 90.
_cell_angle_beta 91.0819(1)
_cell_angle_gamma 90.
_cell_volume 550.36
_cell_formula_units_Z 4
_space_group_name_H-M_alt 'C 1 2/c 1'
_space_group_IT_number 15
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, -y, z+1/2'
2 '-x, -y, -z'
3 '-x, y, -z+1/2'
4 'x, y, z'
5 'x+1/2, -y+1/2, z+1/2'
6 '-x+1/2, -y+1/2, -z'
7 '-x+1/2, y+1/2, -z+1/2'
8 'x+1/2, y+1/2, z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
W6+ 6
In3+ 3
Li1+ 1
O2- -2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_B_iso_or_equiv
_atom_site_occupancy
W1 W6+ 8 f 0.2424(1) 0.08932(8) 0.2506(3) 0.21(2) 1.
In1 In3+ 4 e 0 0.3389(3) 0.25 0.53(4) 1.
Li1 Li1+ 4 e 0.5 0.3412(6) 0.25 1. 1.
O1 O2- 8 f 0.358(1) 0.050(1) 0.938(3) 0.8(1) 1.
O2 O2- 8 f 0.388(1) 0.169(1) 0.387(2) 0.8(1) 1.
O3 O2- 8 f 0.352(1) 0.549(1) 0.943(3) 0.8(1) 1.
O4 O2- 8 f 0.381(1) 0.688(1) 0.404(2) 0.8(1) 1.
#End of TTdata_423127-ICSD