
#(C) 2025 by FIZ Karlsruhe - Leibniz Institute for Information Infrastructure.  All rights reserved.
data_1411-ICSD
_database_code_ICSD 1411
_audit_creation_date 1980-01-01
_audit_update_record 2011-02-01
_chemical_name_common 'Tetralithium plumbate'
_chemical_formula_structural 'Li4 (Pb O4)'
_chemical_formula_sum 'Li4 O4 Pb1'
_chemical_name_structure_type Li4PbO4
_exptl_crystal_density_diffrn 5.01
_citation_title 'Zur Kenntnis von Li4 (Pb O4)'
loop_
_citation_id
_citation_journal_full
_citation_year
_citation_journal_volume
_citation_page_first
_citation_page_last
_citation_journal_id_ASTM
primary 'Zeitschrift fuer Anorganische und Allgemeine Chemie (1950) (DE)' 1977
437 105 115 ZAACAB
loop_
_citation_author_citation_id
_citation_author_name
primary 'Martens, K.P.'
primary 'Hoppe, R.'
_cell_length_a 8.317
_cell_length_b 7.301
_cell_length_c 6.521
_cell_angle_alpha 90.
_cell_angle_beta 90.
_cell_angle_gamma 90.
_cell_volume 395.97
_cell_formula_units_Z 4
_space_group_name_H-M_alt 'C m c m'
_space_group_IT_number 63
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 '-x, y, -z+1/2'
2 '-x, -y, z+1/2'
3 '-x, y, z'
4 '-x, -y, -z'
5 'x, -y, z+1/2'
6 'x, y, -z+1/2'
7 'x, -y, -z'
8 'x, y, z'
9 '-x+1/2, y+1/2, -z+1/2'
10 '-x+1/2, -y+1/2, z+1/2'
11 '-x+1/2, y+1/2, z'
12 '-x+1/2, -y+1/2, -z'
13 'x+1/2, -y+1/2, z+1/2'
14 'x+1/2, y+1/2, -z+1/2'
15 'x+1/2, -y+1/2, -z'
16 'x+1/2, y+1/2, z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
Li1+ 1
Pb4+ 4
O2- -2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_B_iso_or_equiv
_atom_site_occupancy
Li1 Li1+ 8 g 0.145(3) 0.738(1) 0.25 0.9 1.
Li2 Li1+ 8 e 0.148(1) 0 0 1.6 1.
Pb1 Pb4+ 4 c 0 0.3533 0.25 0.33 1.
O1 O2- 8 f 0 0.795(4) 0.022(3) 0.08 1.
O2 O2- 8 g 0.276(2) 0.981(1) 0.25 0.8 1.
#End of TTdata_1411-ICSD